Year 2015,
Volume: 20 Issue: 2, 43 - 56, 25.06.2015
Abstract
In this study raw and degummed silk fabrics are treated with low frequency oxygen plasma and ozone in order to investigate the effects on the physical properties of silk. Plasma and ozone treatments are performed individually and in combined order for 5, 10 and 15 min. The yellowness and whiteness values are determined after the plasma and ozone treatments. The tensile strengths of treated and untreated silk fabrics are measured. The SEM images of the surfaces of silk fabrics are investigated and the combined effect of ozone and plasma treatments are discussed after each test. Results indicate that there is more significant decrease in ozone treatment, considering decrease in whiteness indexes and increase in yellowness values of silk fabrics when compared to the plasma treatment. Generally, when the treatment time of plasma or ozone is increased, increase of yellowness and decrease of whiteness become clear.
Keywords
References
- Avinc O., Eren H.A., Uysal P. et al. (2012) The effects of ozone treatment on soybean fibers, Ozone: Science & Engineering; 34, 143-150.
- Chaiwong C., Tunma S., Sangprasert W. et al. (2010) Graft polymerization of flameretardant compound onto silk via plasma jet, Surface and Coatings Technology, 204, 2991– 2995.
- Eren H.A. and Anis P. (2009) Surface trimer removal of polyester fibers by ozone treatment, Textile Research Journal, 79,652-656.
- Eren H.A. and Öztürk D. (2011) The evaluation of ozonation as an environmentally friendly alternative for cotton preparation, Textile Research Journal, 81,512-519.
- Eren, H.A. and Öztürk D. and Eren S. (2012) After clearing of disperse dyed polyester with gaseous ozone, Coloration Technology,128, 75-81.
- Eren H.A., Avinç O., Uysal P. et al. (2011)The effects of ozone treatment on polylactic acid (PLA) fibres, Textile Research Journal, 81, 1091-1099.
- Fang K., Wang S., Wang C. et al.( 2008) Inkjet printing effects of pigment inks on silk fabrics surface-modified with O2 plasma, Journal of Applied Polymer Science, 107, 2949–2955.
- Freddi G., Mossotti R., Innocenti R., (2003) Degumming of silk fabric with several proteases, Journal of Biotechnology,106,101–112.
- Guohong L., Hong L., Hongshi Z. et al. (2011) Chemical assembly of TiO2 and TiO2@Agnanoparticles on silkfiber to produce multifunctional fabrics, Journal of Colloid and Interface Science, 358, 307–315.
- Gogoi D., Choudhury A.J., Chutia J. et al. (2011) Enhancement of hydrophobicity and tensile strength of muga silk fiber by radiofrequency Ar plasma discharge, Applied Surface Science, 258, 126-135.
- Guan J., Yang C.Q. and Chen G. (2009) Formaldehyde-free flame retardant finishing of silk using a hydroxyl-functional organophosphorus oligomer, Polymer Degradation and Stability, 94, 450–455.
- Ichimura H., Umehara R., Karakawa T. et al. (2005) Animal fiber superior in shrink proofing and method for preparation thereof, US Patent, 6969409.
- Iriyama Y. (2003) Preparation of silk film and its plasma treatment for better dyeability, Journal of Photopolymer Science and Technology, 16, 75-80.
- Kalantzi, D. Mamma and D. Kekos, (2013) Physichochemical and Low Stress Mechanical Properties of Silk Fabrics Degummed by Enzymes, In: Melih Gunay (ed.) Eco-Friendly Textile Dyeing and Finishing. 1th ed. Croatia, Intech, pp: 233-259. Uludağ Üniversitesi Mühendislik Fakültesi Dergisi, Cilt 20, Sayı 2, 2015
- Lee M, Lee MS, Wakida T et al. (2006) Chemical modification of nylon 6 and polyester fabrics by ozone-gas treatment, Journal of Applied Polymer Science, 100, 1344–1348.
- Li G, Liu H, Li T et al. (2012) Surface modification and functionalization of silk fibroin fibers/fabric toward high performance applications, Materials Science and Engineering, 32, 627–636.
- Liu X.S., Xing T.L., Xu D.M. et al. (2012 ) Study on novel eco-friendly anti-creasing agents for natural silk fabric, Chinese Chemical Letters, 23, 665–668.
- Long J.J., Wang H.W., Lu T.Q. et al. (2008) Application of Low-Pressure Plasma Pretreatment in Silk Fabric Degumming Process, Plasma Chemistry and Plasma Processing,28, 701-713.
- McKee T and McKee James R., (2011) Biochemistry: The Molecular Basis of Life, 5th Ed. New York: Oxford, pp:166
- Morent R., Geyter De N., Verschuren J. et al. (2008) Non-thermal plasma treatment of textiles, Surface and Coatings Technology, 202, 3427–3449.
- Ömeroğulları Z. and Kut D. (2012), Application of low-frequency oxygen plasma treatment to polyester fabric to reduce the amount of flame retardant agent, Textile Research Journal, 82, 613-621.
- Ömeroğulları Z. and Kut D. (2012) Flame Retardancy in Textile, Uludağ University Journal of The Faculty of Engineering and Architecture, 17, 27-41.
- Perincek S., Bahtiyari İ., Körlü A. et al. (2007) Ozone bleaching of jute fabrics, AATCC; 7: 34-39.
- Perincek S., Duran K., Korlu A. et al. (2007) An investigation in the use of ozone gas in the bleaching of cotton fabrics, Ozone Science and Engineering, 29,325–333.
- Perincek S., Bahtiyari İ., Körlü A. et al. (2008) Ozone treatment of angora rabbit fiber. Journal of Cleaner Production, 16, 1900-1906.
- Prabaharan M., Rao J.V., Nayar, R. et al. (2000) A study on the advanced oxidation of a cotton fabric by ozone, JSDC, 116, 83-86.
- Sargunami D. and Selvakumar N. (2006) A study on the effects of ozone treatment on the properties of raw and degummed mulberry silk fabrics, Polymer Degradation and Stability, 91, 2644–2653.
- Sargunami D. and Selvakumar N. (2007) Effects of ozone treatment on the properties of raw and degummed tassar silk fabrics, Journal of Applied Polymer Science, 104, 147–155.
- Sargunami D. and Selvakumar N. (2011) Comparative analysis of the effect of ozone treatment on the properties of mulberry and tassar silk fabrics, Journal of the Textile Institute, 102, 870-874.
- Sargunami D. and Selvakumar N. (2012) Effect of ozone treatment on the dyeing properties of mulberry and tassar silk fabrics, Journal of Engineered Fibers and Fabrics, 7, 21-27.
- Shishoo R. (2007) Plasma Technologies for Textiles, England, Cambridge, , pp:13,14,33.
- Tarakçıoğlu, (1983), I. Tekstil Terbiyesi ve Makinaları, Uludağ University, Bursa, Vol.2, Chapter 3, pp 418-439.
- Tieling X., Weilin H., Shiwei L. et al. (2012) Preparation, structure and properties of multifunctional silk via ATRP method, Applied Surface Science, 258, 3208-3213. Balcı, N., Ömeroğulları, Z., Kut, D. ve Eren H.A.: Effects of Plasma and Ozone Treatments on 100% Silk
- Wakida T., Lee M., Jeon J.H. et al. (2004) Ozone-gas treatment of wool and silk fabrics, Sen’i Gakkaishi., 60, 213-219.
- Yu-yue C., Hong L. , Yu R. et al. (2004) Study on Bombyx mori silk treated by oxygen plasma, Zhejiang Univ SCI, 5, 918-922.
- http://www.differencebetween.com/difference-between-oxygen-and-vs-ozone/
- http://www.infrasoil.nl/Afbeeldingen/Perozone/FlyerA4.pdf
Year 2015,
Volume: 20 Issue: 2, 43 - 56, 25.06.2015
Abstract
Bu çalışmada, plazma ve ozonun ipek kumaşın fiziksel özellikleri üzerindeki etkisini araştırmak amacıyla ham ve serisini giderilmiş ipek kumaşlar ozon ve düşük frekanslı oksijen plazma işlemlerine tabi tutulmuştur. Plazma ve ozon işlemleri birbirlerinden bağımsız olarak ve kombine olacak şekilde 5, 10 ve 15 dak. uygulanmıştır. Plazma ve ozon işlemlerinden sonra, sarılık ve beyazlık indeksleri belirlenmiş, kopma mukavemetleri ölçülmüştür. İpek kumaşların yüzeylerinin SEM görüntüleri incelenmiş ve her test ardından ozon ve plazmanın kombine efekti tartışılmıştır. Ozon ve plazma işlemleri karşılaştırıldığında, sonuçlar ipek kumaşların beyazlık indekslerinde azalışın, sarılık değerlerindeki artışın ozonlama işleminde daha belirgin olduğunu ortaya çıkarmıştır. Genel olarak, plazma veya ozonun işlem süreleri arttıkça sarılıktaki artış ve beyazlıktaki azalış daha net bir şekilde görülmektedir.
Keywords
References
- Avinc O., Eren H.A., Uysal P. et al. (2012) The effects of ozone treatment on soybean fibers, Ozone: Science & Engineering; 34, 143-150.
- Chaiwong C., Tunma S., Sangprasert W. et al. (2010) Graft polymerization of flameretardant compound onto silk via plasma jet, Surface and Coatings Technology, 204, 2991– 2995.
- Eren H.A. and Anis P. (2009) Surface trimer removal of polyester fibers by ozone treatment, Textile Research Journal, 79,652-656.
- Eren H.A. and Öztürk D. (2011) The evaluation of ozonation as an environmentally friendly alternative for cotton preparation, Textile Research Journal, 81,512-519.
- Eren, H.A. and Öztürk D. and Eren S. (2012) After clearing of disperse dyed polyester with gaseous ozone, Coloration Technology,128, 75-81.
- Eren H.A., Avinç O., Uysal P. et al. (2011)The effects of ozone treatment on polylactic acid (PLA) fibres, Textile Research Journal, 81, 1091-1099.
- Fang K., Wang S., Wang C. et al.( 2008) Inkjet printing effects of pigment inks on silk fabrics surface-modified with O2 plasma, Journal of Applied Polymer Science, 107, 2949–2955.
- Freddi G., Mossotti R., Innocenti R., (2003) Degumming of silk fabric with several proteases, Journal of Biotechnology,106,101–112.
- Guohong L., Hong L., Hongshi Z. et al. (2011) Chemical assembly of TiO2 and TiO2@Agnanoparticles on silkfiber to produce multifunctional fabrics, Journal of Colloid and Interface Science, 358, 307–315.
- Gogoi D., Choudhury A.J., Chutia J. et al. (2011) Enhancement of hydrophobicity and tensile strength of muga silk fiber by radiofrequency Ar plasma discharge, Applied Surface Science, 258, 126-135.
- Guan J., Yang C.Q. and Chen G. (2009) Formaldehyde-free flame retardant finishing of silk using a hydroxyl-functional organophosphorus oligomer, Polymer Degradation and Stability, 94, 450–455.
- Ichimura H., Umehara R., Karakawa T. et al. (2005) Animal fiber superior in shrink proofing and method for preparation thereof, US Patent, 6969409.
- Iriyama Y. (2003) Preparation of silk film and its plasma treatment for better dyeability, Journal of Photopolymer Science and Technology, 16, 75-80.
- Kalantzi, D. Mamma and D. Kekos, (2013) Physichochemical and Low Stress Mechanical Properties of Silk Fabrics Degummed by Enzymes, In: Melih Gunay (ed.) Eco-Friendly Textile Dyeing and Finishing. 1th ed. Croatia, Intech, pp: 233-259. Uludağ Üniversitesi Mühendislik Fakültesi Dergisi, Cilt 20, Sayı 2, 2015
- Lee M, Lee MS, Wakida T et al. (2006) Chemical modification of nylon 6 and polyester fabrics by ozone-gas treatment, Journal of Applied Polymer Science, 100, 1344–1348.
- Li G, Liu H, Li T et al. (2012) Surface modification and functionalization of silk fibroin fibers/fabric toward high performance applications, Materials Science and Engineering, 32, 627–636.
- Liu X.S., Xing T.L., Xu D.M. et al. (2012 ) Study on novel eco-friendly anti-creasing agents for natural silk fabric, Chinese Chemical Letters, 23, 665–668.
- Long J.J., Wang H.W., Lu T.Q. et al. (2008) Application of Low-Pressure Plasma Pretreatment in Silk Fabric Degumming Process, Plasma Chemistry and Plasma Processing,28, 701-713.
- McKee T and McKee James R., (2011) Biochemistry: The Molecular Basis of Life, 5th Ed. New York: Oxford, pp:166
- Morent R., Geyter De N., Verschuren J. et al. (2008) Non-thermal plasma treatment of textiles, Surface and Coatings Technology, 202, 3427–3449.
- Ömeroğulları Z. and Kut D. (2012), Application of low-frequency oxygen plasma treatment to polyester fabric to reduce the amount of flame retardant agent, Textile Research Journal, 82, 613-621.
- Ömeroğulları Z. and Kut D. (2012) Flame Retardancy in Textile, Uludağ University Journal of The Faculty of Engineering and Architecture, 17, 27-41.
- Perincek S., Bahtiyari İ., Körlü A. et al. (2007) Ozone bleaching of jute fabrics, AATCC; 7: 34-39.
- Perincek S., Duran K., Korlu A. et al. (2007) An investigation in the use of ozone gas in the bleaching of cotton fabrics, Ozone Science and Engineering, 29,325–333.
- Perincek S., Bahtiyari İ., Körlü A. et al. (2008) Ozone treatment of angora rabbit fiber. Journal of Cleaner Production, 16, 1900-1906.
- Prabaharan M., Rao J.V., Nayar, R. et al. (2000) A study on the advanced oxidation of a cotton fabric by ozone, JSDC, 116, 83-86.
- Sargunami D. and Selvakumar N. (2006) A study on the effects of ozone treatment on the properties of raw and degummed mulberry silk fabrics, Polymer Degradation and Stability, 91, 2644–2653.
- Sargunami D. and Selvakumar N. (2007) Effects of ozone treatment on the properties of raw and degummed tassar silk fabrics, Journal of Applied Polymer Science, 104, 147–155.
- Sargunami D. and Selvakumar N. (2011) Comparative analysis of the effect of ozone treatment on the properties of mulberry and tassar silk fabrics, Journal of the Textile Institute, 102, 870-874.
- Sargunami D. and Selvakumar N. (2012) Effect of ozone treatment on the dyeing properties of mulberry and tassar silk fabrics, Journal of Engineered Fibers and Fabrics, 7, 21-27.
- Shishoo R. (2007) Plasma Technologies for Textiles, England, Cambridge, , pp:13,14,33.
- Tarakçıoğlu, (1983), I. Tekstil Terbiyesi ve Makinaları, Uludağ University, Bursa, Vol.2, Chapter 3, pp 418-439.
- Tieling X., Weilin H., Shiwei L. et al. (2012) Preparation, structure and properties of multifunctional silk via ATRP method, Applied Surface Science, 258, 3208-3213. Balcı, N., Ömeroğulları, Z., Kut, D. ve Eren H.A.: Effects of Plasma and Ozone Treatments on 100% Silk
- Wakida T., Lee M., Jeon J.H. et al. (2004) Ozone-gas treatment of wool and silk fabrics, Sen’i Gakkaishi., 60, 213-219.
- Yu-yue C., Hong L. , Yu R. et al. (2004) Study on Bombyx mori silk treated by oxygen plasma, Zhejiang Univ SCI, 5, 918-922.
- http://www.differencebetween.com/difference-between-oxygen-and-vs-ozone/
- http://www.infrasoil.nl/Afbeeldingen/Perozone/FlyerA4.pdf
There are 37 citations in total.
Details
| Primary Language | English |
|---|---|
| Journal Section | Research Articles |
| Authors | |
| Publication Date | June 25, 2015 |
| Submission Date | June 25, 2015 |
| Published in Issue | Year 2015 Volume: 20 Issue: 2 |
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